Chinese scientists discover thin-layered graphene in Chang’e-5 lunar samples

Chinese scientists analyzing one of the lunar samples brought back in 2021 by Chang’e-5 from the Moon’s near side have detected for the first time what they call “natural few-layered graphene.”

You can read the paper here. The samples from Chang’e-5 came from some of what are believed are some of the youngest lava on the Moon. This discovery confirms that conclusion. From the paper:

The identification of graphene in the core–shell structure suggests a bottom-up synthesis process rather than exfoliation, which generally involves a high-temperature catalytic reaction. Therefore, a formation mechanism of few-layer graphene and graphitic carbon is proposed here.

Volcanic eruption, a typical high-temperature process, occurred on the Moon. Lunar soil can be stirred up by solar wind and high-temperature plasma discharge can be generated on the Moon’s surface. … [T]he Fe-bearing mineral particles, such as olivine and pyroxene, in lunar soil might catalyse the conversion of carbon-containing gas molecules in the solar wind or polycyclic aromatic hydrocarbons into graphitic carbon of different thicknesses and morphologies on their surfaces, including few-layer graphene flakes and carbon shells.

These graphene flakes are likely to disappear over time, so its existence reinforces the belief that this lava is young.

Unlike too many American planetary scientists recently — who have repeatedly implied that finding anything even remotely related to life processes suggests the possibility of life on Venus and Mars — the Chinese scientists don’t make the additional absurd claim that finding carbon on the Moon suggests the existence of life. It doesn’t. Kudos to them for being good scientists.

As a result, expect American mainstream media to pay no attention to this result, despite its intriguing and unprecedented nature.

A new technique for creating diamonds

In discovering a new solid state for carbon scientists have also discovered that it is a relatively inexpensive way to produce diamonds.

Professor Jay Narayan of North Carolina State University is the lead author of three papers describing the work that sees Q-carbon join the growing list of carbon solids, a list that includes graphite, graphene, fullerene, amorphous carbon and diamond. He has suggested that the only place Q-carbon might be found in the natural world is in the core of certain planets.

The researchers created Q-carbon by starting with a thin plate of sapphire (other substrates, such as glass or a plastic polymer, will also work). Using a high-power laser beam, they coated the sapphire with amorphous carbon, a carbon form with no defined crystalline structure. They then hit the carbon with the laser again, raising its temperature to about 4,000 Kelvin, and then rapidly cooled, or quenched, the melted carbon. This stage of quenching is where “Q” in Q-carbon comes from.

The researchers have found that, depending on the substrates, tiny diamonds will form within the Q-carbon, suggesting to me that they have actually discovered how diamonds are formed deep below the Earth. The hot high pressure environment there allows Q-carbon to naturally form, and in the process of its solidification diamonds are a byproduct.